https://wiki.taigi.ima.org.tw/w/index.php?action=history&feed=atom&title=%E5%85%AB%E6%B0%AF%E5%90%88%E4%BA%8C%E5%AD%B5%E9%85%B8%E9%89%80
八氯合二孵酸鉀 - 修訂紀錄
2026-05-07T19:53:30Z
本 wiki 上此頁面的修訂紀錄
MediaWiki 1.43.1
https://wiki.taigi.ima.org.tw/w/index.php?title=%E5%85%AB%E6%B0%AF%E5%90%88%E4%BA%8C%E5%AD%B5%E9%85%B8%E9%89%80&diff=369033&oldid=prev
TaiwanTonguesApiRobot：從 JSON 檔案批量匯入
2025-08-22T04:30:32Z
<p>從 JSON 檔案批量匯入</p>
<table style="background-color: #fff; color: #202122;" data-mw="interface">
<col class="diff-marker" />
<col class="diff-content" />
<col class="diff-marker" />
<col class="diff-content" />
<tr class="diff-title" lang="zh-Hant-TW">
<td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">←上個修訂</td>
<td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">於 2025年8月22日 (五) 12:30 的修訂</td>
</tr><tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l1">第1行：</td>
<td colspan="2" class="diff-lineno">第1行：</td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>'''八氯合二孵酸鉀'''<del style="font-weight: bold; text-decoration: none;">，</del>是一<del style="font-weight: bold; text-decoration: none;">種含有四重鍵的</del>配合物，化學式為 K <del style="font-weight: bold; text-decoration: none;">二 [Re </del>二 Cl 八<del style="font-weight: bold; text-decoration: none;">]</del>。<del style="font-weight: bold; text-decoration: none;">伊</del>的<del style="font-weight: bold; text-decoration: none;">結構是</del>由<del style="font-weight: bold; text-decoration: none;">美國無機化學家堀蘭克 </del><del style="font-weight: bold; text-decoration: none;">・ </del><del style="font-weight: bold; text-decoration: none;">阿爾伯特 </del><del style="font-weight: bold; text-decoration: none;">・ 科頓（F . A . Cotton</del>）<del style="font-weight: bold; text-decoration: none;">佇一九六四年測定（陰</del>離子<del style="font-weight: bold; text-decoration: none;">結</del>構<del style="font-weight: bold; text-decoration: none;">如圖所示）</del>。 <del style="font-weight: bold; text-decoration: none;">頂司軌道理論認為</del>這<del style="font-weight: bold; text-decoration: none;">離子</del>的四重鍵會當<del style="font-weight: bold; text-decoration: none;">表示 </del><del style="font-weight: bold; text-decoration: none;">σ </del>二 <del style="font-weight: bold; text-decoration: none;">π </del>四 <del style="font-weight: bold; text-decoration: none;">δ </del>二，<del style="font-weight: bold; text-decoration: none;">也就是包括一个 </del><del style="font-weight: bold; text-decoration: none;">σ </del><del style="font-weight: bold; text-decoration: none;">鍵、兩个 </del><del style="font-weight: bold; text-decoration: none;">π </del>鍵<del style="font-weight: bold; text-decoration: none;">佮</del>一<del style="font-weight: bold; text-decoration: none;">个 δ </del><del style="font-weight: bold; text-decoration: none;">鍵</del>。</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>'''八氯合二孵酸鉀'''是一<ins style="font-weight: bold; text-decoration: none;">个</ins>配合物<ins style="font-weight: bold; text-decoration: none;">件</ins>，化學式為 K <ins style="font-weight: bold; text-decoration: none;">四 Mo </ins>二 Cl 八。<ins style="font-weight: bold; text-decoration: none;">這款紅色</ins>的<ins style="font-weight: bold; text-decoration: none;">鹽</ins>由<ins style="font-weight: bold; text-decoration: none;">鉀離子佮八氯合二孵酸根（Mo </ins><ins style="font-weight: bold; text-decoration: none;">二 Cl </ins><ins style="font-weight: bold; text-decoration: none;">八十四 </ins><ins style="font-weight: bold; text-decoration: none;">−</ins>）離子構<ins style="font-weight: bold; text-decoration: none;">成</ins>。這<ins style="font-weight: bold; text-decoration: none;">種物質有歷史</ins>的<ins style="font-weight: bold; text-decoration: none;">意義喔因為伊是上早發現有</ins>四重鍵<ins style="font-weight: bold; text-decoration: none;">的化合物之一。這種鹽通常以二水合物形式做甲。</ins></div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div> </div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;">該化合物</ins>會當<ins style="font-weight: bold; text-decoration: none;">看著六鼻基礎經兩步的反應製甲：</ins></div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div> </div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div> </div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;">: 二 Mo ( CO ) 六 + 四 HO 二 CCH 三 → Mo 二 ( O 二 CCH 三 ) 四 + 二 H 二 + </ins><ins style="font-weight: bold; text-decoration: none;">十二 CO</ins></div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div> </div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div> </div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;">: Mo </ins>二 <ins style="font-weight: bold; text-decoration: none;">( O </ins><ins style="font-weight: bold; text-decoration: none;">二 CCH 三 ) </ins>四 <ins style="font-weight: bold; text-decoration: none;">+ </ins><ins style="font-weight: bold; text-decoration: none;">四 HCl + 四 KCl → K 四 Mo 二 Cl 八 + 四 HO </ins>二 <ins style="font-weight: bold; text-decoration: none;">CCH 三乙酸鹽佮鹽酸的反應上早認為產生三角勢酸鹽</ins>，<ins style="font-weight: bold; text-decoration: none;">毋過隨後的晶體學分析證實該物質中有 D 四 h 對稱性的 Mo 二 Cl </ins><ins style="font-weight: bold; text-decoration: none;">八十四 </ins><ins style="font-weight: bold; text-decoration: none;">− </ins><ins style="font-weight: bold; text-decoration: none;">離子。Mo—Mo </ins>鍵<ins style="font-weight: bold; text-decoration: none;">長是二交</ins>一<ins style="font-weight: bold; text-decoration: none;">四 </ins><ins style="font-weight: bold; text-decoration: none;">Å</ins>。</div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>==參考資料==</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>==參考資料==</div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>[[分類: 待校正]]</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>[[分類: 待校正]]</div></td></tr>
<!-- diff cache key taigi_wiki:diff:1.41:old-368398:rev-369033:php=table -->
</table>
TaiwanTonguesApiRobot
https://wiki.taigi.ima.org.tw/w/index.php?title=%E5%85%AB%E6%B0%AF%E5%90%88%E4%BA%8C%E5%AD%B5%E9%85%B8%E9%89%80&diff=368398&oldid=prev
TaiwanTonguesApiRobot：從 JSON 檔案批量匯入
2025-08-22T04:25:05Z
<p>從 JSON 檔案批量匯入</p>
<p><b>新頁面</b></p><div>'''八氯合二孵酸鉀'''，是一種含有四重鍵的配合物，化學式為 K 二 [Re 二 Cl 八]。伊的結構是由美國無機化學家堀蘭克 ・ 阿爾伯特 ・ 科頓（F . A . Cotton）佇一九六四年測定（陰離子結構如圖所示）。 頂司軌道理論認為這離子的四重鍵會當表示 σ 二 π 四 δ 二，也就是包括一个 σ 鍵、兩个 π 鍵佮一个 δ 鍵。<br />
<br />
==參考資料==<br />
<br />
[[分類: 待校正]]</div>
TaiwanTonguesApiRobot